Interference of Light
October 19, 21, and 23
Light behaves as a transverse wave, as discussed a few lectures ago. In the microscope in plane polarized light (PPL) waves of light can be:
In phase: particles in the same wave train are in phase if, at any and all times, they are always displaced from the rest position by the same amount and direction.
Out of phase: particles whose vibrational displacements are equal but opposite in direction are out of phase.
Path difference: the distance between two points on the same wave path is known as their path difference. In phase waves have a path difference (D) of nl
Out of phase waves have D = (2n+1)/2l
When waves are neither in or out of phase, they must interfere and combine to form a composite wave with amplitude R. Their vibrational vectors add vectorially where they coincide in time and space. The form of the resultant wave depends on the wavelengths of the two original waves, their amplitudes, and their path difference.
Anisotropic Crystals
The refractive index (and therefore velocity of light) in an anisotropic mineral depends on the direction of light vibration.
When PPL enters an anisotropic crystal, the light is resolved immediately and breaks into two rays - fast and slow.
Rays do not interfere while in the crystal, but when the light reaches the edge of the crystal, there are two resulting perpendicular vibration directions. The waves interfere immediately once they leave the crystal.
In the crystal: 1) the slow ray has an index of refraction N
2) the fast ray has an index of refraction n. N > n
3) the path difference D between fast and slow is zero, and the fast travels faster once in the crystal and comes out on top first.
If the crystal thickness is t and the time for passage of the slow ray is TN and the fast ray is Tn, TN < Tn
While waiting for the slow ray to emerge, the fast ray speeds onward, and the separation distance is c(TN-Tn) where c = speed of light. Velocities in the crystal are cN = t/TN, cn = t/Tn such that
D = ct/cN - ct/cn = t (N-n). Note that N- n = the birefringence for the mineral
The resultant ray at the top of the crystal is plane polarized, circularly polarized, or elliptically polarized. Depending on which type of polarization is present, the light may or may not get transmitted by the upper polarizer/analyzer.
1) Plane polarization of the resultant wave
1/frequency = period of a wave - the time required for the series of vibrations necessary to complete one full wavelength.
2 cases for the difference between the two waves:
2) Circular polarization of the resultant wave
D = 1/4 l, 3/4 l, ... (2n+1)/4 l
In this case, the interference produces a wave with constant displacement vectors but varying azimuthals - i.e. like the thread of a screw.
3) Elliptical polarization of the resultant wave
D = all above cases. The resultant wave spirals upwards and the vibrational vectors are of constant length.
Viewed down the beam, the wave will appear elliptical
Above the crystal, the fast and slow waves interfere by vector addition. In some cases, we will treat the resultant wave as two vector components the came out of the crystal.
Next, the resultant wave encounters the upper analyzer. The percentage of transmitted light can be calculated using the following variables:
% transmission = [-sin2 *(180º*D)/l * sin2(t-90º)]*100 assuming no absorption of light and 90º polarizers
if t = 45º, % transmission = (sin2 *(180º*D)/l)*100
transmission % is at a maximum when D = 1/2l, 1 ½l, 2 ½l incident light is rotated 90º and all passes through the analyzer.
transmission % is at a minimum when D = nl - no rotation of the incident beam and all light is killed at the analyzer
EXTINCTION
Isotropic minerals are always extinct in XN (crossed polarizers)
Anisotropic crystals:
Because of interference of fast and slow rays upon emergence, the plane of polarization generally wont be the same as that of the incident light.
When there is no rotation by the crystal, the grain is extinct in XN. This occurs 4 times when the grain is rotated 360º (every 90º) and maximum brightness is at 45º to the extinction.
INTERFERENCE COLORS
If the illumination source for the microscope is white light, anisotropic minerals will be colored in XN. These colors are interference colors that result from the unequal transmission of light by the analyzer of the component wavelengths of white light. The colors depend upon the path difference in the crystal for the wavelength of light produced.
Suppose that D = 550 nm, t = 45º, and the illumination is white light. Consider only the wavelengths 400.0, 440.0, 488.9, 550.0, 628.6, and 733.3 nm
For l = 400, D = 550 -> 1 3/8 l 95% transmitted
For l = 440, D = 550 -> 1 1/4 l 50%
For l = 488.9, D = 550 -> 1 1/8 l 17%
For l = 550, D = 550 -> 1l Extinguished
For l = 628.6, D = 550 -> 7/8 l 17%
For l = 733.3, D = 550 -> ¾ l 50%
In this case, the red and violet are transmitted, and green and yellow are eliminated, resulting in a reddish violet color.
See the chart in K&H or Nesse of the colors that are associated with the various path differences and thin section thickness.