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Lecture 13: DISTRIBUTION OF OCEAN SEDIMENTS

Biogenic oozes- review- important (we will revisit later)
Summary -- general distribution
RESOURCES OF THE SEA FLOOR
Continental margin
Deep-sea floor
Law of the Sea Treaty

Powerpoint Lecture Slides


Distribution of biogenous oozes:

1. Production in surface waters:
Biological productivity controlled by nutrients -- N and P
"Upwelling" brings nutrients to surface waters
Productivity high in upwelling zones

2. Dissolution in deep waters
Deep waters "undersaturated" -- particles tend to dissolve
"Carbonate Compensation Depth" (CCD)
Calcareous oozes absent below CCD
Atlantic: ~ 4,000 m
Pacific: ~ 500 - 1,500 m
Siliceous particles dissolve more slowly; nutrients more important than depth

3. Dilution by other sediments
High input of terrigenous sediment
"Dilutes" biogenous components to < 30 %

SUMMARY -- Distribution of sediment on the sea floor (modern sediments)

RESOURCES OF THE SEA FLOOR

Economic considerations determine profitability/viability of each type

Continental margins
Building materials
Phosphate deposits
Hydrocarbons (fossil fuels)
Present operations
Origin of petroleum and natural gas
Production and deposition
Accumulation in areas of high sedimentation rate
Alteration during burial (>100°C)
Continental margins -- target for all offshore production
Cost
Poor preservation of organic matter in deep sea
Sulfur (salt domes)
 
Deep-sea floor
Manganese nodules
Limitations to development:
Depressed global markets
High costs
Ownership of sea floor
Recent Gold Mining Activity- Black Smoker "Chimney" Deposits(?)
 
Law of the Sea Treaty (United Nations, l982)
Ownership of sea-bed resources and fisheries
Provisions:
Exclusive Economic Zones (EEZ)
Regulation of deep-sea by UN Commision
Response (to date) of USA


Distribution of biogenous oozes:

The distribution of biogeneous sediments is controlled by three important processes:

1. Production in surface waters: The growth of marine algae (which are the base of the oceanic food chain) is controlled principally by the availability of two critical nutrient elements -- N (nitrogen) and P (phosphorus). These critical nutrients are mostly supplied to surface waters by deep waters that "upwell" to the surface. Therefore, biological productivity is high in areas of strong vertical upwelling -- along the equator, in certain coastal regions, and in the Southern Ocean around Antarctica.

2. Dissolution in deep waters: Deep-ocean waters are undersaturated in calcium carbonate and opalline silica. Therefore, biogenic particles tend to dissolve as they settle through the water column and as they sit on sea floor. This effect is more pronounced for calcareous sediments. In fact, calcareous oozes are absent below a certain depth called the "Carbonate Compensation Depth, or CCD. The depth of the CCD varies from ocean to ocean. It occurs at 4,000 m in the Atlantic. The CCD is shallower in the Pacific, at depths of 500 - 1,500 m. Siliceous particles dissolve more slowly as they sink and are not limited in distribution by depth as much. Nutrient supply more important in controlling the distribution of siliceous sediments.

3. Dilution: Calcareous and siliceous components can be diluted to
< 30 % of the total sediment (and therfore not qualify as a "biogenous ooze") in regions where the input of terrigenous sediment is very high. This occurs along continental margins -- surface productivity is high and dissolution is minimal, but biogenous oozes don't occur because of the high influx of terrigenous sediment from continents

SUMMARY -- Distribution of sediment on the sea floor (modern sediments)

Terrigenous: - - continental margins and adjacent abyssal plains.
Manganese nodules: - - deep basins, especially the Pacific.
Red Clay: - - deep ocean regions where not diluted by biogenic particles.
Calcareous oozes: - - wide-spread in relatively shallow areas of the deep sea.
Siliceous oozes: - - polar and equatorial bands where nutrients are supplied to surface waters by vertical upwelling.

RESOURCES OF THE SEA FLOOR

Economic considerations dictate whether a potentially useful material is developed as a resource (whether on land or in the oceans). Questions that must be addressed for a potential marine resource are:
(1) Is there a market for the material?
(2) Will extra costs of offshore production be offset by profits?

Resources of the Continental Margin

Building materials - - Bulk materials such as sand and gravel as well as CaCO3 shell deposits (for cement) represents the largest off-shore operation in terms of gross production. But the success of such ventures is tied to the proximity of materials to markets. Thus, the most cost-efficient operation are in bays and along beaches, and along the inner continental shelves near major markets.

Phosphate deposits - - The element phosphorus is important component of fertilizer. Phosphates deposits are recovered from the sea floor. These occur as calcium-phosphate muds, sands, and nodules on some continental shelves and slopes.

Hydrocarbons (fossil fuels) - - Petroleum (liquid) and natural gasare the most valuable resource of the sea bed. One-third of the estimated global reserves of oil and gas are in continental margin sediments.
At present, offshore recovery hydrocarbons is going on in the USA (Gulf Coast, California, north slope of Alaska), the North Sea, the Arabian/Persian Gulf, Indonesia, and Australia. Many other areas of potential production have not yet been explored.

How do economically important hydrocarbon deposits form?

Sediment of planktonic organic matter is deposited. (This is only a very small fraction of organic matter produced in surface waters -- the rest is eaten and decomposed in marine food chains.)

Rapid accumulation of sediment on margins preserves deposited organic matter from decomposition.

The organic matter is altered to liquid and gaseous hydrocarbons as sediment is buried to high temperatures (>100 C).

Continental margins will always be the target of offshore recovery because:
Drilling is in relatively shallow waters, the costs are less.
Preservation of organic matter in deep-sea pelagic sediments is poor.

Sulfur - - in its elemental form is an important industrial chemical. Elemental sulfur is often found on the top of subsurface geologic structures called "salt domes." Salt domes often occur along continental margins and adjacent on-land coastal areas, like the Gulf Coast of USA and Mexico. The salt (mostly halite) was deposited during the initial stages of continental rifting. In addition to a source for elemental sulfur, salt domes are also natural "traps" for petroleum and natural gas.

Resources of the Deep-Sea Floor:

Manganese nodules - - are potentially important sources for the metals Mn, Co, Cu, Ni. There has already breen considerable investment in locating concentrations of manganese nodules ion the seas floor and developing technologies for processesing nodules as sea. But there are currently limitations to the development of manganese-nodule mining:
(a) Depressed global markets for metals.
(b) High cost of development.
(b) Ownership of "found" deposits on the deep-sea floor.

Recent Gold Mining Activity- Black Smoker "Chimney" Deposits -- An australian company recently developed plans to mine gold from a vast deposit of minerals formed by "black smokers" on the sea floor. Plans include blasting the "chimney" deposits with explosives, recovering the fragments by dredging, then refining these ores on-shore.

"Law of the Sea" Treaty (United Nations, 1982) was developed to address the question of ownwership and to regulate development of seabed resources. Some of its provisions are:
200-mile Exclusive Economic Zone. In that area, countries have the exclusive right to develop all marine resources (fisheries included). Unfortunately, there is considerable overlap between EEZ's, and consequently disputes between nations about who owns what (e.g., USA vs Canada and Cuba
UN Seabed Authority regulates deep-sea mining; profits shared among all countries.

The USA and other developed countries did not agree to profit-sharing; they have licensed their own multinational companies for development.


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